张絜

博士，研究员，博士生导师，河南师范大学特聘教授

Email:   jie.zhang@htu.edu.cn

教育经历:

博士, 中国科学院兰州化学物理研究所，1999

硕士, 中国科学院青海盐湖研究所，1996

科研经历：

2013/09—          河南师范大学，化学化工学院，研究员，特聘教授

2010/11—2013/08，美国俄亥俄国家生化试剂公司，研究员，研发部主任

2004/04—2010/10，美国布鲁克黑文国家实验室，辛辛那提大学，研究员

2001/06—2004/03，英国诺丁汉大学，化学系，研究员

1999/08—2001/06，中国科学院化学研究所，博士后

主讲课程：

高等无机化学, 无机化学前沿

研究领域与兴趣：

金属有机合成化学，硼化学，均相催化反应机理

近年来主持的主要科研项目：

国家自然科学基金资助项目(2016.01-2019.12)：“新型硼氮空间受阻路易斯酸碱对的合成及其在催化还原二氧化碳中的应用”, 批准号：21571052.

河南省重点科技攻关项目(2015.01-2016.12)：“新型硼氮空间受阻路易斯酸碱对的合成与催化性能研究”, 批准号：152102210085.

近期代表性论文：

1.  Jiarui Chang, Fei Fang, Jie Zhang*, Xuenian Chen*,  “Hydrosilylation of Aldehydes and Ketones Catalysed by Bis(phosphinite) Pincer Platinum Hydride Complexes”, Adv. Synth. Catal. 2020, 362, 2709–2715.

2.  Yan-Na Ma, Yan Gao, Yi Jing, Jiaxin Kang, Jie Zhang*, Xuenian Chen*, “Syntheses of Bromo‑N‑heterocycles through DibromohydantoinPromoted Tandem C−H Amination/Bromination”, J. Org. Chem. 2020, 85, 2918–2926.

3.  Bula Cao, Yazhou Ding, Fei Fang, Jiarui Chang, Jie Zhang*, Shujun Li, Xuenian Chen*, “The stability of group 10 metal POCOP pincer complexes: decomposition/reconstruction pathways of the pincer backbone”, Dalton Trans. 2019, 48, 13760–13768.

4.  Yazhou Ding, Qiang-Qiang Ma, Jiaxin Kang, Jie Zhang*, Shujun Li, Xuenian Chen*, Palladium(II) complexes supported by PBP and POCOP pincer ligands: a comparison of their structure, properties and catalytic activity, Dalton Trans. 2019, 48, 17633–17643.

5.  Xi-Meng Chen, Jin Wang, Si-Cong Liu, Jie Zhang*, Donghui Wei*, Xuenian Chen*, “Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH₃BH₃ with NaH and the mechanistic study”, Dalton Trans. 2019, 48, 14984–14988.

6.  Yan-Na Ma, Yajing Bian, Xin Liu, Jie Zhang*, Xuenian Chen*, “One-Pot Synthesis of Iodo-Dibenzothiazines from 2‑Biaryl Sulfides”, J. Org. Chem. 2019, 84, 450−457. 

7.  Shujun Li, Yue Zhao, Huihui Qi, Yanfang Zhou, Shuxia Liu, Xiaoming Ma, Jie Zhang*, Xuenian Chen*, “Boronic acid derivatized lanthanide–polyoxometalates with novel B–OH–Ln and B–O–Nb bridges”,  Chem. Commun. 2019, 55, 2525−2528.

8.      Jie Zhang*, Ting Liu, Qiang-Qiang Ma, Shujun Li, Xuenian Chen*, “A reaction of [2,6-(^tBu₂PO)₂C₆H₃]NiSCH₂Ph with BH₃·THF: borane mediated C–S bond cleavage”, Dalton Trans. 2018, 47, 6018–6024.

9.      Jie Zhang*, Ting Liu, Changgeng Wei, Jiarui Chang, Qiang-Qiang Ma, Shujun Li, Nana Ma*, Xuenian Chen*, “The Reactivity of Mercapto Groups against Boron Hydrides in Pincer Ligated Nickel Mercapto Complexes”, Chem. Asian J. 2018, 13, 3231–3238.

10.  Yan-Na Ma, Chen-Yang Guo, Qianyi Zhao, Jie Zhang*, Xuenian Chen*, “Synthesis of dibenzothiazines from sulfides by one-pot N,O-transfer and intramolecular C–H amination”,  Green Chem. 2018, 20, 2953–2958.

11.  Xi-Meng Chen, Nana Ma, Qian-Fan Zhang, Jin Wang, Xiaoge Feng, Changgeng Wei, Lai-Sheng Wang*, Jie Zhang*, Xuenian Chen*, “Elucidation of the Formation Mechanisms of the Octahydrotriborate Anion (B₃H₈⁻) through the Nucleophilicity of the B−H Bond” J. Am. Chem. Soc. 2018, 140, 6718−6726.

12.  Ting Liu, Wenjuan Meng, Qiang-Qiang Ma, Jie Zhang*, Huizhen Li, Shujun Li, Qianyi Zhao, Xuenian Chen*, “Hydroboration of CO₂ Catalyzed by Bis(phosphinite) Pincer Ligated Nickel Thiolate Complexes”, Dalton Trans. 2017, 46, 4504−4509.

13.  Qiang-Qiang Ma, Ting Liu, Anubendu Adhikary, Jie Zhang*, Jeanette A. Krause, Hairong Guan*, “Using CS₂ to Probe the Mechanistic Details of Decarboxylation of Bis(phosphinite)-Ligated Nickel Pincer Formate Complexes”, Organometallics 2016, 35, 4077−4082.

14.  Qiang-Qiang Ma, Ting Liu, Shujun Li, Jie Zhang*, Xuenian Chen*, Hairong Guan*, “Highly Efficient Reduction of Carbon Dioxide with a Borane Catalyzed by Bis(phosphinite) Pincer Ligated Palladium Thiolate Complexes”, Chem. Commun. 2016, 52, 14262−14265.

15.  Hou-Ji Cao, Qianyi Zhao, Qian-Fan Zhang, Jiaxuan Li, Ewan J. M. Hamilton, Jie Zhang*, Lai-Sheng Wang*, Xuenian Chen*, “Catalyst Design Based on Agostic Interactions: Synthesis, Characterization, and Catalytic Activity of Bis(pyrazolyl)borate Copper Complexes”, Dalton Trans. 2016, 45, 10194−10199.

16.  Huizhen Li, Nana Ma, Wenjuan Meng, Judith Gallucci, Yongqing Qiu, Shujun Li, Qianyi Zhao, Jie Zhang*, Ji-Cheng Zhao*, Xuenian Chen*, “Formation Mechanisms, Structure, Solution Behavior and Reactivity of Aminodiborane”, J. Am. Chem. Soc. 2015, 137, 12406−12414.