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国家有突出贡献的中青年专家 王键吉教授
国家有突出贡献的中青年专家 王键吉教授
发布时间: 2016-06-14 浏览次数: 426

王键吉个人简介

  

    王键吉博士、教授、博士生导师,河南师范大学原校长,国家有突出贡献的中青年专家、河南省优秀专家、中原学者、河南省杰出青年基金、杰出人才基金获得者、河南省优秀科技创新人才获得者,中国化学会理事、中国化学会化学热力学专业委员会副主任、中国化工学会离子液体专业委员会副主任、国家自然科学基金委化学学科评审组成员、化学重点学科第一学术带头人、绿色化学介质与反应教育部重点实验室主任,J. Chem. Theromydn., Chin. J. Chem. Phys. 编委.

  

  

教育与研究经历:

1975-1978年,河南师范大学(原新乡师范学院),化学系,大学

1978-1981年,河南师范大学(原新乡师范学院)化学系,研究生/硕士

1999-2001年,日本横滨国立大学,化学与材料工程系, 研究生/博士

1981-1987年,河南师范大学,化学化工学学院,助教、讲师

1987-1989年,英国London大学,大学学院化学系,访问学者

1987-1991年,河南师范大学,化学化工学学院,副教授

1992-1994年,英国Surrey大学,化学系,Research Fellow

1992-至今,河南师范大学,化学化工学学院,教授、博士生导师

联系方式:

电话:0373-3325805

E-mail: Jwang@henannu.edu.cn

  

主讲课程:

《物理化学》、《物理化学新进展》、《绿色化学》

研究领域与兴趣:

1. 功能溶液化学

2. 基于离子液体的绿色化学

3. 生物质新能源高效利用

近年来主持的主要科研项目:

1. 国家863项目(2007AA05Z454): 离子液体分级处理木质纤维素原料制备燃料乙醇和氢能新技术

2. 国家973前期专项(2011CB211702):功能离子液体低温溶解/催化木质素生成液态烷烃燃料的研究

3. 国家863项目(子课题)( 2004AA649030):基于离子液体的酸性有害气体资源化利用的新技术—功能化离子液体的制备与物性研究

4. 国家973项目(子课题)( 2009CB219902) 离子液体的合成、表征及物理化学性质研究

5. 国家自然科学基金重点项目(21133009):离子液体复杂体系化学热力学与分子间相互作用研究

6. 国家自然科学基金(21273062: pH 响应离子液体的溶液化学研究

7. 国家自然科学基金(20873036):离子液体双水相的微观结构与萃取分离性能研究

8. 国家自然科学基金(20573034):室温离子液体在溶液中的簇集行为研究

9. 国家自然科学基金(20273019):室温离子液体中溶质-溶剂相互作用规律研究

10. 国家自然科学基金(29973009):锂电池电解质溶液中离子溶剂化的热力学和谱学研究

11. 国家自然科学基金(29573102):水溶液中电解质-糖相互作用规律的热力学研究

12. 国家教委优秀年轻教师资助计划: 氨基酸在蛋白质变性剂水溶液中的热力学和传输性质研究

13. 教育部高等学校骨干教师: 锂电池电解质溶液的结构与性能

14. 教育部高等学校博士点专项科研基金(20060476003):咪唑类离子液体在分子溶剂中的溶剂化学行为研究

15. 河南省杰出青年基金: 水溶液中电解质糖-模型生物分子相互作用的热力学研究

16. 河南省杰出人才计划(08420050015):功能化离子液体的设计、合成及对生物大分子的选择性分离

17. 河南省中原学者计划(092101510300):离子液体在绿色分离和先进材料制备中的作用机制研究

18. 日本三菱化学公司研发基金: 液态和胶态介质中离子迁移数测定方法和实验装置的研究与开发

  

代表性论文与专利:

论文:

 J.Am.Chem. Soc., Angew. Chem. Int. Ed., Chem. Soc. Rev., Chem. Eur. J., Chem.Comm., Green Chem., Environ.Sci.Technol., J.Phys.Chem., ChemSusChemSCI期刊发表论文200余篇,被SCI引用3700余次,代表性论文如下:

1.张虎成,张立伟,王键吉, Grafting and Coloring onto Silver Nanoparticles by Photoinduced Surface Modification, J. Am. Chem. Soc., 131 (37), 1320613207 (2009)

  

2.任运来,闫孟杰,王键吉,张宗超,姚开胜,Selective Reductive Cleavage of Inert Aryl C-O Bonds by an Iron Catalyst, Angew. Chem. Int. Ed., 52, 12674-12678 (2013).

  

3.张锁江,孙剑,张晓春,辛加余,苗晴晴,王键吉,Ionic Liquid-based Green Processes for Energy Production, Chem. Soc. Rev, 2014, DOI: 10.1039/c3cs60409h

  

4.裴渊超,王键吉,轩小朋,樊静,范貌宏,Factors affecting ionic liquids based removal of anionic dyes from water, Environ. Sci. Technol., 41, 5090-5095 (2007)

  

5.王慧勇,张腊梅,王键吉,李志勇,张锁江,The First Evidence for Unilamellar Vesicle Formation of Ionic Liquids in Aqueous Solutions, Chem. Commun., 49, 5222-5224 (2013)

  

6.姚开胜,卢伟伟,李鑫莹,王键吉,元炯亮,Tunable Synthesis of Ag Films at Ionic Liquid-aqueous Interfaces,Chem. Commun., 49, 1398-1400(2013).

  

7.王慧勇,王键吉,范貌宏,Extraction of Ionic Liquids from Aqueous Solutions by Humic Acid: An Environmentally Benign, Inexpensive and Simple Procedure,Chem. Commun., 48, 392-394 (2012).

  

8. 卢伟伟,宋应利,姚开胜,王键吉,Thermal-Induced Formation of a Three-Dimensional

Nanoplasmonic Sensor from Ag Nanocubes with High Stability and Reusability, Chem. Eur. J., 20, 3636-3645 (2014).

  

9.熊大珍,王慧勇,李志勇,王键吉, Recovery of Ionic Liquids with Aqueous Two-Phase Systems Induced by Carbon Dioxide, ChemSusChem., 5, 2255-2261 (2012).

  

10.吕本莲,许爱荣,王键吉,Cation Does Matter: How Cationic Structure Affects the Dissolution of Cellulose in Ionic Liquids, Green Chem., 16, 1326-1335 (2014)

  

11.熊大珍,李志勇,王慧勇,王键吉,Selective Separation of Aliphatic and Aromatic Amines with CO2 Switchable Ionic Liquids Aqueous Two-phase Systems,Green Chem., 15, 1941-1948 (2013).

  

12.李志勇,刘欣欣,裴渊超,王键吉,Design of Environmentally Friendly Ionic Liquids Aqueous Two-phase Systems for the Efficient and High Activity Extraction of Proteins, Green Chem., 14, 2941-2950 (2012).

  

13.陈清泰,许爱荣,李志勇,王键吉,Influence of Anionic Structure on the Dissolution of Chitosan in 1-butyl-3-methylimidazolium-based Ionic Liquids, Green Chem., 13, 3446-3452 (2011).

  

14.朱安莲,李凌君,王键吉,卓克垒,Direct Nucleophilic Substitution Reaction of Alcohols Mediated by a zinc-based Ionic Liquid, Green Chem., 13, 1244-1250 (2011).

  

15.姚开胜,李鑫莹,卢伟伟,王键吉,Tailoring the Properties of Aqueous/Ionic Liquids Interface for Tunable Synthesis and Self-Assembly of ZnS Nanoparticles, J. Mater. Chem. A,2, 5140-5148 (2014).

  

16.王慧勇,冯青琴,王键吉,张虎成,Salt Effect on the Aggregation Behavior of 1-Decyl-3-methylimidazolium Bromide in Aqueous Solutions J. Phys. Chem. B, 1141380-13879 (2010).

  

17.赵玉灵,刘晓敏,王键吉,张锁江,Insight into Co-solvent Effect of Cellulose Dissolution in Imidazolium-based Ionic Liquid Systems,J. Phys. Chem. B, 117, 9042-9049.

  

18.赵玉灵,刘晓敏,吕兴梅,张锁江,王键吉,The Behavior of Ionic Liquids under High Pressure: A Molecular Dynamics Simulation, J. Phys. Chem. B, 116, 10876-10884 (2012).

  

19.赵扬,高山娇,王键吉,汤俊明,Aggregation of Ionic Liquids [Cnmim]Br (n = 4, 6, 8, 10, 12) in D2O: A NMR Study, J. Phys. Chem. B, 112, 2031-2039 (2008).

  

20.王键吉,王慧勇,张社利,张虎成,赵扬,Conductivities, Volumes, Fluorescence and Aggregation Behavior of Ionic Liquids [C4mim][BF4] and [Cnmim]Br (n=4, 6, 8, 10, 12) in Aqueous Solutions, J. Phys. Chem. B, 111, 6181-6188 (2007).

  

21.张虎成, 王键吉,郑洪河,卓克垒,赵扬,Interactions of Nanosized Al2O3 and ZnO with Poly(ethylene oxide)-NaSCN Polymer Electrolytes, J. Phys. Chem. B, 109, 2610-2616 (2005).

22.张虎成,轩小朋,王键吉,汪汉卿,Vibrational Spectroscopic Studies on Interactions in PEO- NaSCN-urea Composites, J. Phys. Chem. B, 108, 1563-1569 (2004).

  

23.郑勇,轩小朋,王键吉,范貌宏,The Enhanced Dissolution of β-Cyclodextrin in Some Hydrophilic Ionic Liquids J. Phys. Chem. A, 114, 3926-3931 (2010).

  

24.轩小朋,张虎成,王键吉,汪汉卿, Vibrational Spectroscopic and Density Functional Studies on Ion Solvation and Association of Lithium Tetrafluorobrate in Acetonitrile, J. Phys. Chem. A, 108, 7513-7521 (2004).

  

25.许爱荣,王键吉,王慧勇,Effects of Anionic Structure and Lithium Salts Addition on the Dissolution of Cellulose in 1-butyl-3-methylimidazolium-based Ionic Liquid Solvent Systems, Green Chem., 12, 268-275 (2010)

  

26.王键吉, 裴渊超,赵扬,胡治国,Recovery of Amino Acids by Imidazolium Based Ionic Liquids from Aqueous Media, Green Chem., 7, 196-202 (2005)

  

27.王键吉,田勇,赵扬, 卓克垒,A Volumetric and Viscosity Study for the Mixtures of 1-n-butyl- 3- methylimidazolium Tetrafluoroborate Ionic Liquid with Acetonitrile, Dichloromethane, 2-Butanone and N,N-dimethylformamide, Green Chem., 5, 618-622 (2003)

  

28.张新迎,范学森,牛红英,王键吉,An Ionic Liquid as a Recyclable Medium for the Green Preparation of α, α’-bis (substituted benzylidene)cycloalkanones Catalyzed by FeCl3·6H2O, Green Chem., 5, 267-269 (2003).

  

29.吴长增,王键吉,李志勇,荆俊,王慧勇,Relative Hydrophobicity between the Phases and Partition of Cytochrome-c in Glycine Ionic Liquids Aqueous Two-phase Systems,J. Chromat. A., 1305, 1-6 (2013).

  

30.吴长增,王键吉,王慧勇,裴渊超,李志勇, Effect of Anionic Structure on the Phase Formation and Hydrophobicity of Amino Acid Ionic Liquids Aqueous Two-phase Systems, J. Chromat. A., 1218, 8587-8593 (2011)

  

31.李志勇,裴渊超,王慧勇,樊静,王键吉, Ionic liquids based aqueous two-phase systems and their applications in green separation process, Trends Anal. Chem., 29, 1336-1346 (2010).

  

32.王慧勇,王键吉,张社利,裴渊超,卓克垒,Ionic Association of the Ionic Liquids [C4mim][BF4], [C4mim][PF6], and [Cnmim]Br in Molecular Solvents. ChemPhysChem., 10, 251625232 (2009)

33.王慧勇,王键吉,张仕彪,Binding Gibbs Energy of Ionic Liquids to Calf thymus DNA: a Fluorescence Spectroscopy Study, Phys. Chem. Chem. Phys., 13, 3906-3910 (2011)

  

34.赵玉灵,刘晓敏,王键吉,张锁江,Effects of Anionic Structure on the Dissolution of Cellulose in Ionic Liquids Revealed by Molecular Simulation, Carbonhydrate Polymers, 94, 723-730 (2013).

  

35.许爱荣,张亚娟,赵扬,王键吉,Cellulose Dissolution at Ambient Temperature: Role of Preferential Solvation of Cations of Ionic Liquids by a Cosolvent, Carbonhydrate Polymers, 92, 540-544 (2013).

  

36.赵扬,崔桂荣,王键吉,范貌宏, Effects of Ionic Liquids on the Characteristics of Synthesized Nano Fe(0) Particles, Inorg. Chem., 48, 1043510441 (2009)

37.赵扬,陈震华,王慧勇,王键吉,Crystallization Control of CaCO3 by Ionic Liquids in Aqueous Solution, Crystal Growth & Design, 9, 4984-4986 (2009)

  

  

38.李鑫莹,姚开胜,卢伟伟,王键吉,Facile Interfacial Synthesis of Gold Micro/nanostructures and Their Applications for Efficient Surface Enhanced Raman Scattering , CrystEngComm, 15, 1289-1292 (2013).

  

39.周海梅,吕萍,申圆圆,王键吉,樊静,Identification of Degradation Products of Ionic Liquids in an Ultrasound Assisted Zero-valent iron Activated Carbon Micro-electrolysis System and Their Degradation Mechanism, Water Res., 47, 3514-3522 (2013) .

  

40.周海梅,申圆圆,吕萍,王键吉,樊静,Degradation of 1-butyl-3-methylimidazolium Chloride Ionic Liquid by Ultrasound and Zero-valent iron/activated Carbon, Separ. Purif. Technol.,104, 208-213 (2013).

  

41.裴渊超,王键吉,武坤,轩小朋,卢新杰,Ionic Liquid-based Aqueous Two-phase Extraction of Selected Proteins, Separ. Purif. Technol.,64, 288-295 (2009)

42. 樊静,范云场,裴渊超,武坤,王键吉, Solvent Extraction of Selected Endocrine-disrupting Phenols using Ionic Liquids, Sep. Purif. Technol., 61 324-331 (2008)

43.张虎成, 王键吉, 轩小朋,卓克垒,FT-IR Studies on Interactions of AlCl3 with PEO-NaSCN Polymer Electrolytes, Electrochim. Acta, 51, 3244-3248 (2006)

44.轩小朋, 王键吉,汪汉卿, Theoretical Insights into PF6- and its Alkali Metal Ion Pairs: Geometries and Vibrational Frequencies, Electrochim. Acta, 50, 4196-4201 (2005)

45.轩小朋, 王键吉,赵扬,朱建军,Experimental and Computational Studies on the Solvation of Lithium Tetrafluorobrate in Dimethylsulfoxide, J. Raman Spectrosc., 38, 865-872 (2007)

46.轩小朋,张虎成,王键吉,汪汉卿, Raman Spectroscopic and DFT Studies on Solutions of NaBF4 in N,N-dimethylformamide, J. Raman Spectrosc., 34, 465-470 (2003)

47.冯青琴,王慧勇,张仕彪,王键吉,Aggregation Behavior of 1-Dodecyl-3-methylimidazolium Bromide Ionic Liquid in non-aqueous Solvents, Colloids and Surfaces A: Physicochem. Eng. Aspects, 367, 7-11 (2010)

48.轩小朋, 王键吉,赵扬,张虎成, FT-Raman Spectroscopic Evidences for the Preferential Solvation of Sodium Tetrafluorobrate in Acetonitrile-based Mixed Solvents, Spectrochim. Acta A, 62, 500-505 (2005)

49.王键吉,吴艳平,轩小朋,汪汉卿, Ion-molecule Interactions in Solutions of Lithium Perchlorate in Propylene Carbonate + Diethyl Carbonate Mixtures: an IR and Molecular Orbital Study, Spectrochim. Acta, A, 58, 2097-2104 (2002)

50.朱安莲,王键吉,韩丽君,范貌宏, Measurements and Correlation of Viscosities and Conductivities for the Mixtures of Imidazolium Ionic Liquids with Molecular Solutes, Chem. Eng. J., 147, 27-35 (2009)

51.王键吉,张仕彪,王慧勇,裴渊超, Apparent Molar Volumes and Electrical Conductance of Ionic Liquids [Cnmim]Br (n=8, 10, 12) in Ethylene Glycol, N,N-Dimethylformamide, and Dimethylsulfoxide at 298.15 K, J. Chem. Eng. Data, 54, 3252-3258 (2009)

52.吴长增,王键吉,裴渊超,王慧勇,李志勇,Salting-Out Effect of Ionic Liquids on Poly(propylene glycol) (PPG): Formation of PPG + Ionic Liquid Aqueous Two-Phase Systems, J. Chem. Eng. Data, 55, 5004-5008 (2010)

53.裴渊超,王键吉,刘丽,武坤,赵扬,Liquid-liquid Equilibria of Aqueous Biphasic Systems Containing Selected Imidazolium Ionic Liquids and Salts, J. Chem. Eng. Data, 52, 2026-2031 (2007)

54.李志勇,裴渊超,刘丽,王键吉, (Liquid+liquid) Equilibria for (Acetate-based Ionic Liquids + Inorganic Salts) Aqueous Two-phase Systems, J. Chem. Thermodyn. 2010, 42, 932-937 (2010)

55.王键吉,朱安莲,赵扬,卓克垒,Excess Molar Volumes and Excess Logarithm Viscosityes for Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluophosphate with Some Organic Compounds, J. Solution Chem., 34, 585-596 (2005)

专利:

1.樊静,吴春来,王键吉,彭传云,魏娅方,梁峰,茜素紫键合硅胶固相萃剂的合成方法,中国发明专利,专利号: ZL 200710054167.6

  

2.刘振, 王键吉, 尹卫平, 杨敏,天然纤维素原料经离子液体分级处理一步发酵制备乙醇的方法,中国发明专利,专利号:ZL 200810095798.7

  

3.刘振,王键吉,尹卫平,任运来,任云利,利用离子液体生产乙醇的方法,中国发明专利,专利号:ZL201010030128.4

  

4.刘振,王键吉,郝静静,陈竞一,常庆辉,一种磁场辅助气提发酵生产乙醇的方法,中国发明专利,专利号: ZL 201110171615.7

  

5.刘振,王键吉,常庆辉,陈竞一,张辉,孙鲜明,马建华,一种发酵制氢中氢气的分离装置,中国实用新型专利,专利号:ZL 201220353776.8

6.王键吉,许爱荣,樊静,轩小朋,一种纤维素的溶剂,中国发明专利,申请号:200910065084.6

  

著作:

张锁江, 王键吉, 吕兴梅, 周清,Structures and Interactions of Ionic Liquids, Springer, 2014

  

成果奖励:

1. 离子液体的构效关系及其化学工程基础研究, 2010年国家自然科学二等奖

2. 糖和氨基酸与电解质弱相互作用的热力学研究,2004年河南省科技进步一等奖

3. 锂离子电池电解质的微观结构研究,2009年河南省科技进步一等奖